8. Identifying isotopes

Could the trail be due to a molecule? Two atoms of hydrogen bound to a single neon atom would measure 22 on this scale, but to produce the weak trail at 11 the molecule would need to have gained a double charge by losing a second electron. Thomson knew it was very unusual for a molecule to lose a second electron.

Another theory, which also relied on a molecule carrying a double charge, was that the 22 trace could be due to doubly ionised carbon dioxide. Thomson removed all the carbon dioxide from the gas, but the trace was still present.

Thomson correctly interpreted the traces as showing isotopes of neon. The trace at 20 was ionised neon, as expected, but the trace at 22 was also ionised neon. The two types of neon were chemically identical but their masses were different. The trace at 11 was this second type of neon which had lost two electrons. Isotopes of radioactive elements had already been discovered by Soddy in Canada, but this was the first demonstration that a non-radioactive element could have isotopes.

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