4. Positive ions

At first Thomson could only produce a single line on his photographs. From its position Thomson calculated it was the hydrogen ion that Wien had found, as its mass to charge ratio was two thousand times greater than the electron. Even if the discharge tube contained other gases, only this hydrogen line was produced.

It looked like ions of hydrogen were carrying positive charge in the same way that electrons carried negative charge, but Thomson wanted to be sure. By using a very large discharge tube at very low pressure, he managed to produce a second line, with twice the specific charge of the hydrogen ion.

Thomson identified this ion as an ionised hydrogen molecule. Two atoms of hydrogen bond together to form a molecule. When it becomes ionised one electron is lost, producing one positive charge on the ion, but its mass is twice that of the hydrogen atom. This means that the specific charge of the ionised molecule is half the specific charge of an ionised hydrogen atom.

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